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- Chemical Name: Stab
CAS No.: 56553-60-7
Molecular Fomula: C6H10BNaO6
Molecular weight: 211.94
Appearance: White Powder
Sample: Available
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Description of Stab
- Sodium triacetoxyborohydride, also known as sodium triacetoxyhydroborate, commonly abbreviated STAB, is a chemical compound with the formula Na(CH3COO)3BH. Like other borohydrides, it is used as a reducing agent in organic synthesis.
- This colourless salt is prepared by protonolysis of sodium borohydride with acetic acid:
NaBH4 + 3 HO2CCH3 → NaBH(O2CCH3)3 + 3 H2
Owing to the steric and electronic effects of the acetoxy groups, sodium triacetoxyborohydride is a milder reducing agent than sodium borohydride or even sodium cyanoborohydride. Furthermore, NaBH(OAc)3 avoids the toxic side-products generated by sodium cyanoborohydride. Sodium triacetoxyborohydride is especially suitable for reductive aminations of aldehydes and ketones. - However, unlike sodium cyanoborohydride, the triacetoxyborohydride is water-sensitive, and water cannot be used as a solvent with this reagent, nor is it compatible with methanol. It reacts only slowly with ethanol and isopropanol and can be used with these.
NaBH(OAc)3 may also be used for reductive alkylation of secondary amines with aldehyde-bisulfite adducts.
Basic Info of Triacetoxyborohydride
Basic Info
Numbering system
Properties
Safety Info
Basic Info
Chemical Name | Sodium Triacetoxyborohydride |
CAS No. | 56553-60-7 |
Molecular Formula | C6H10BNaO6 |
Molecular Weight | 211.94100 |
PSA | 78.90000 |
LogP | -0.60710 |
Numbering system
UNII | 4VU0JE4YSK |
Properties
Appearance & Physical State | white crystalline powder |
Melting Point | 114-118ºC |
Water Solubility | reacts |
Stability | Reacts violently with water. |
Storage Condition | Flammables + water-Freezer (-20ºC)e area |
Safety Info
Appearance & Physical State | white crystalline powder |
Melting Point | 114-118ºC |
Water Solubility | reacts |
Stability | Reacts violently with water. |
Storage Condition | Flammables + water-Freezer (-20ºC)e area |
What is Triacetoxyborohydride?
- With the progress of science and technology and the development of society, chemical products have invariably permeated our daily lives, in medicine, food, cosmetics, electronics, industry, and other areas, becoming an essential part of our lives. One such product is Stab which has developed particularly rapidly in recent years. Do you know about Stab?
- The official answerSodium triacetoxyborohydride is an organic compound with the structural formula (CH3COO)3BHNa. it is a white crystalline powder. It is soluble in benzene and tetrahydrofuran. It is a mild and selective borohydride reagent. Reacts with water and is soluble in acetonitrile and 1,2-dichloroethane. Used for amination reduction reactions of ketones and aldehydes, reductive amination/lactonization of carbonyl complexes and amines, and reductive amination of aryl aldehydes
What’s the application of Triacetoxyborohydride?
Sodium triacetoxyborohydride, white crystalline powder; soluble in benzene, used in amination reduction reactions of ketones and aldehydes, reductive amination/lactonization of carbonyl complexes and amines, and reductive amination of aryl aldehydes Chemical book. Sodium triacetoxyborohydride is mainly used for the amination reduction reaction of ketones and aldehydes, the reductive amination/lactonization of carbonyl complexes and amines, and the reductive amination of aryl aldehydes.
Conclusion
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